I would like to understand how can I drive an effective Tech discovery session (just had a PRD walkthrough) with the team (remotely working) before we start writing a detailed system design document. The engineers are mostly L4 and are still learning how to effectively collaborate instead of full blown meeting.
Which company are you working in?
In terms of how to structure the tech discovery session, I'd think about this in terms of ownership that mirrors what you anticipate in the actual project. You may have a rough idea in your head about domain ownership (frontend, backend, API, etc), so those people should naturally lead the discovery in that domain.
Similar to any brainstorm, I'd have an expansion and contraction phase, where you list various tools / technologies which may work (expansion) and separately from that start to document which of these is actually feasible or not (contraction)